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An Operationally Simple and Efficient Work-up Procedure for TBAF-mediated Desilylation; Application to Halichondrin Synthesis

An operationally simple and efficient work-up method for TBAF-mediated TBS-deprotection has been developed. The procedure includes addition of a sulfonic acid resin and calcium carbonate, followed by filtration and evaporation. This method eliminates the tedious aqueous-phase extraction process to r...

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Detalhes bibliográficos
Main Authors: Kaburagi, Yosuke, Kishi, Yoshito
Formato: Artigo
Idioma:Inglês
Publicado em: 2007
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2519602/
https://ncbi.nlm.nih.gov/pubmed/17286380
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol063113h
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