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Second Generation Synthesis of C27-C35 Building Block of E7389, A Synthetic Halichondrin Analog
[Image: see text] A practical method is reported to synthesize E7389 C27-C35 building block (13) from 1,2-O-isopropylidene-α-D-5-deoxyglucurono-6,3-lactone (3). This synthesis relies on two key processes: (1) C34/C35-diol is introduced via asymmetric dihydroxylation with dr = 3:1, with the undesired...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2759418/ https://ncbi.nlm.nih.gov/pubmed/19754145 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol9016589 |
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