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Tandem Carbocupration/Oxygenation of Terminal Alkynes
[Image: see text] A direct and general synthesis of α-branched aldehydes and their enol derivatives is described. Carbocupration of terminal alkynes and subsequent oxygenation with lithium tert-butyl peroxide generates a metallo-enolate. Trapping with various electrophiles provides α-branched aldehy...
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| 主要な著者: | , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2005
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2519174/ https://ncbi.nlm.nih.gov/pubmed/16321021 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol052413g |
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