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The reaction of adenosylcobalamin-dependent glutamate mutase with 2-thiolglutarate
We have investigated the reaction of glutamate mutase with the glutamate analog, 2-thiolglutarate. In the standard assay, 2-thiolglutarate behaves as a competitive inhibitor with K(i) = 0.05 mM. However, rather than simply binding inertly at the active site, 2-thiolglutarate elicits cobalt-carbon bo...
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| Main Authors: | , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2517135/ https://ncbi.nlm.nih.gov/pubmed/16981724 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi061067n |
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