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Characterization of a Succinyl-CoA Radical–Cob(II)alamin Spin Triplet Intermediate in the Reaction Catalyzed by Adenosylcobalamin-Dependent Methylmalonyl-CoA Mutase()

The electron paramagnetic resonance (EPR) spectrum of an intermediate freeze trapped during the steady state of the reaction catalyzed by the adenosylcobalamin (AdoCbl)-dependent enzyme, methylmalonyl-CoA mutase, has been studied. The EPR spectrum is that of a hybrid triplet spin system created as a...

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Detalhes bibliográficos
Main Authors: Mansoorabadi, Steven O., Padmakumar, Rugmini, Fazliddinova, Nisso, Vlasie, Monica, Banerjee, Ruma, Reed, George H.
Formato: Artigo
Idioma:Inglês
Publicado em: 2005
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3132558/
https://ncbi.nlm.nih.gov/pubmed/15736925
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi0482102
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