A carregar...
Reductive Olefination of Aldehydes via Chromium-Brook Rearrangement
The combination of CrCl(2) and silyl chlorides converts aryl and conjugated aldehydes into olefinic adducts in good to excellent yields. When constrained by structural features, the intermediate vic-diol can be isolated. Available data are consistent with a novel chromium-Brook rearrangement.
Na minha lista:
| Main Authors: | , , , , |
|---|---|
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
|
| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2517130/ https://ncbi.nlm.nih.gov/pubmed/16805524 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol0607140 |
| Tags: |
Adicionar Tag
Sem tags, seja o primeiro a adicionar uma tag!
|