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Reductive Olefination of Aldehydes via Chromium-Brook Rearrangement
The combination of CrCl(2) and silyl chlorides converts aryl and conjugated aldehydes into olefinic adducts in good to excellent yields. When constrained by structural features, the intermediate vic-diol can be isolated. Available data are consistent with a novel chromium-Brook rearrangement.
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| Autors principals: | , , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2006
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2517130/ https://ncbi.nlm.nih.gov/pubmed/16805524 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol0607140 |
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