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Ring Expansion/Homologation-Aldehyde Condensation Cascade using tert-Trihalomethylcarbinols
[Figure: see text] Treatment of cyclic tert-trihalomethylcarbinols with CrCl(2) in THF/HMPA in the presence of aryl or aliphatic aldehydes initiates a cascade sequence of one carbon ring expansion-olefination affording conjugated exo-cyclic ketones. Acyclic tert-trihalomethylcarbinols undergo a comp...
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| Main Authors: | , , , , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2517229/ https://ncbi.nlm.nih.gov/pubmed/16986971 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol061953q |
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