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Dioldehydrase: an Essential Role for Potassium Ion in the Homolytic Cleavage of the Cobalt-Carbon Bond in Adenosylcobalamin

The complex of dioldehydrase with adenosylcobalamin (Coenzyme B(12)) and potassium ion reacts with molecular oxygen in the absence of a substrate to oxidize coenzyme and inactivate the complex. In this paper, high performance liquid chromatography and mass spectral analysis are used to identify the...

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Detalhes bibliográficos
Main Authors: Schwartz, Phillip A., Frey, Perry A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2007
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2516201/
https://ncbi.nlm.nih.gov/pubmed/17516630
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi700078z
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