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5′-Peroxyadenosine and 5′-Peroxyadenosylcobalamin as Intermediates in the Aerobic Photolysis of Adenosylcobalamin.
The photolysis of adenosylcobalamin (coenzyme B(12)) results in homolytic cleavage of the Co-C5′ bond, forming cob(II)alamin and the 5′-deoxyadenosyl radical. In the presence of molecular oxygen, it has been proposed that the primary reaction is interception of the 5′-deoxyadenosyl radical by O(2) t...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2553253/ https://ncbi.nlm.nih.gov/pubmed/17503776 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi700077v |
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