A carregar...
Synthesis of (+)-Bullatacin via the Highly Diastereoselective [3+2] Annulation Reaction of a Racemic Aldehyde and a Non-Racemic Allylsilane
A total synthesis of (+)-bullatacin has been accomplished via a diastereoselective [3+2] annulation reaction of the highly enantiomerically enriched allylsilane 3 and racemic aldehyde 4, which provides the key bis-tetrahydrofuran fragment 15 with ≥ 20 : 1 ds.
Na minha lista:
| Main Authors: | , , , , |
|---|---|
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2005
|
| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2507730/ https://ncbi.nlm.nih.gov/pubmed/16146398 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol051719k |
| Tags: |
Adicionar Tag
Sem tags, seja o primeiro a adicionar uma tag!
|