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Synthesis and Structural Reassignment of (+)-Epicalyxin F
We have established the structure of (+)-epicalyxin F through chemical synthesis. An acid promoted rearrangement of synthetic benzopyran 6 led to the identification of the natural product as (3S,5S,7R)-epicalyxin F (22). Comparison with NMR spectra and optical rotation of the natural product confirm...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2496922/ https://ncbi.nlm.nih.gov/pubmed/17958435 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol702200t |
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