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Understanding the mechanism of Pd-catalyzed allylic substitution of the cyclic difluorinated carbonates
We present a mechanistic investigation of Pd-catalyzed allylic substitution of cyclic gem-difluorinated carbonates 1 and 4, previously employed in the synthesis of 3',3'-difluoro-2'-hydroxymethyl-4',5'-unsaturated carbocyclic nucleosides in 17 steps. The substitution feature...
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| Main Authors: | , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Beilstein-Institut
2008
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2486488/ https://ncbi.nlm.nih.gov/pubmed/18941489 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.4.18 |
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