The Reactivity Patterns of Low-Coordinate Iron Hydride Complexes

We report a survey of the reactivity of the first isolable iron-hydride complexes with a coordination number less than five. The high-spin iron(II) complexes [(β-diketiminate)Fe(μ-H)](2) react rapidly with representative cyanide, isocyanide, alkyne, N(2), alkene, diazene, azide, CO(2), carbodiimide...

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Main Authors: Yu, Ying, Sadique, Azwana R., Smith, Jeremy M., Dugan, Thomas R., Cowley, Ryan E., Brennessel, William W., Flaschenriem, Christine J., Bill, Eckhard, Cundari, Thomas R., Holland, Patrick L.
Formato: Artigo
Idioma:Inglês
Publicado: 2008
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC2474859/
https://ncbi.nlm.nih.gov/pubmed/18444648
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja710669w
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