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Isotope Effects and the Mechanism of Epoxidation of Cyclohexenone with tert-Butyl Hydroperoxide
The mechanism of the epoxidation of 2-cyclohexen-1-one with tert-butyl hydroperoxide mediated by DBU was studied by a combination of experimental kinetic isotope effects and theoretical calculations. A large (12)C/(13)C (k(12(C))/k(13(C))) isotope effect of ≈1.032 was observed at the C(3) (β) positi...
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| Autors principals: | , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2007
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2465813/ https://ncbi.nlm.nih.gov/pubmed/17608437 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo070777b |
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