A carregar...
Isotope Effects and the Mechanism of Epoxidation of Cyclohexenone with tert-Butyl Hydroperoxide
The mechanism of the epoxidation of 2-cyclohexen-1-one with tert-butyl hydroperoxide mediated by DBU was studied by a combination of experimental kinetic isotope effects and theoretical calculations. A large (12)C/(13)C (k(12(C))/k(13(C))) isotope effect of ≈1.032 was observed at the C(3) (β) positi...
Na minha lista:
| Main Authors: | , , , |
|---|---|
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
|
| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2465813/ https://ncbi.nlm.nih.gov/pubmed/17608437 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo070777b |
| Tags: |
Adicionar Tag
Sem tags, seja o primeiro a adicionar uma tag!
|