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Transition State Geometry Measurements from (13)C Isotope Effects. The Experimental Transition State for the Epoxidation of Alkenes with Oxaziridines

We suggest here and evaluate a methodology for the measurement of specific interatomic distances from a combination of theoretical calculations and experimentally measured (13)C kinetic isotope effects. This process takes advantage of a broad diversity of transition structures available for the epox...

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Hlavní autoři: Hirschi, Jennifer S., Takeya, Tetsuya, Hang, Chao, Singleton, Daniel A.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2009
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2640442/
https://ncbi.nlm.nih.gov/pubmed/19146405
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja8088636
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