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Extending the motif of the [FeFe]-hydrogenase active site models: Protonation of Fe(2)(NR)(2)(CO)(6–)(x)L(x) species
Studies on diiron dithiolato complexes have proven fruitful for modeling the active site of the [FeFe]-hydrogenases. Here we present a departure from the classical Fe(2)S(2) motif by examining the viability of Fe(2)N(2) butterfly compounds as functional models for the diiron active site of [FeFe]-hy...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2007
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2440487/ https://ncbi.nlm.nih.gov/pubmed/17606299 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jinorgbio.2007.05.005 |
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