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Synthesis of Resorcinol Derived Spironitronates

Syntheses of several unique spironitronates are reported. The key transformation involves the first known example of an ipso oxidative cyclization of nitro functionality. Oxidation proceeds from both o-and p-phenols. Reductions of these compounds provide novel spiroisoxazoline derivatives.

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Detalhes bibliográficos
Main Authors: Marsini, Maurice A., Huang, Yaodong, Van De Water, Ryan W., Pettus, Thomas R. R.
Formato: Artigo
Idioma:Inglês
Publicado em: 2007
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2435179/
https://ncbi.nlm.nih.gov/pubmed/17645344
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol0710257
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