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A Diastereoselective Formal Synthesis of Berkelic Acid
[Image: see text] A formal synthesis of berkelic acid is reported. The strategy employs the combination of a chiral exocyclic enol ether and an achiral isochromanone to afford the chroman spiroketal core via a base-triggered generation and cycloaddition of an o-quinone methide intermediate. Other ke...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3107127/ https://ncbi.nlm.nih.gov/pubmed/21138313 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol102652t |
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