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Entropy—enthalpy compensation: Fact or artifact?

The phenomenon of entropy–enthalpy (S-H) compensation is widely invoked as an explanatory principle in thermodynamic analyses of proteins, ligands, and nucleic acids. It has been suggested that this compensation is an intrinsic property of either complex, fluctuating, or aqueous systems. The questio...

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Autore principale: Sharp, Kim
Natura: Artigo
Lingua:Inglês
Pubblicazione: Cold Spring Harbor Laboratory Press 2001
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC2374136/
https://ncbi.nlm.nih.gov/pubmed/11344335
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