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Iron-oxidation-state-dependent O-O bond cleavage of meta-chloroperbenzoic acid to form an iron(IV)-oxo complex
The mechanism of formation of [Fe(IV)(O)(N4Py)](2+) (2, N4Py = N,N-bis(2-pyridylmethyl)-N-bis(2-pyridyl)methylamine) from the reaction of [Fe(II)(N4Py)(CH(3)CN)](2+) (1) with m-chloroperbenzoic acid (mCPBA) in CH(2)Cl(2) at −30 °C has been studied on the basis of the visible spectral changes observe...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2352149/ https://ncbi.nlm.nih.gov/pubmed/18443654 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.ica.2007.07.039 |
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