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Pd(OAc)(2)-catalyzed domino reactions of 1,2-dihaloarenes and 2-haloaryl arenesulfonates with Grignard reagents: efficient synthesis of substituted fluorenes

Pd(OAc)(2)-catalyzed domino reactions of 1,2-dihalobenzenes and 2-haloaryl arenesulfonates with hindered Grignard reagents to form substituted fluorenes, which are believed to occur through palladium associated aryne intermediates, is described. Such palladium associated aryne reaction pathway was f...

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Main Authors: Dong, Cheng-Guo, Hu, Qiao-Sheng
格式: Artigo
語言:Inglês
出版: 2008
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC2350206/
https://ncbi.nlm.nih.gov/pubmed/19279672
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2008.01.020
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