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Attempted hydrogen–deuterium exchange of the protio-trimethyloxonium dication (CH(3))(3)OH(2+), study of methylating ability of (CH(3))(3)O(+) in superacids and theoretical investigations
Attempted hydrogen–deuterium exchange of trimethyloxonium ion, (CH(3))(3)O(+) with excess of 1:1 (2)HF/SbF(5) superacid at −30°C over a period of 30 days showed no exchange. Theoretical calculations at the MP2/6–31G** level are in accord with the lack of hydrogen–deuterium exchange in the methyl gro...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
The National Academy of Sciences
1998
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC22448/ https://ncbi.nlm.nih.gov/pubmed/9539696 |
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