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Attempted hydrogen–deuterium exchange of the protio-trimethyloxonium dication (CH(3))(3)OH(2+), study of methylating ability of (CH(3))(3)O(+) in superacids and theoretical investigations

Attempted hydrogen–deuterium exchange of trimethyloxonium ion, (CH(3))(3)O(+) with excess of 1:1 (2)HF/SbF(5) superacid at −30°C over a period of 30 days showed no exchange. Theoretical calculations at the MP2/6–31G** level are in accord with the lack of hydrogen–deuterium exchange in the methyl gro...

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Main Authors: Olah, George A., Rasul, Golam, Burrichter, Arwed, Prakash, G. K. Surya
Format: Artigo
Jezik:Inglês
Izdano: The National Academy of Sciences 1998
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC22448/
https://ncbi.nlm.nih.gov/pubmed/9539696
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