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Structures and stabilities of higher coordinate onium-boronium dications (X(+)BH(3)(+) and X(+)BH(5)(+); X = NH(3), PH(3), H(2)O, and H(2)S)
Structures of higher coordinate onium-boronium dications (X(+)BH(3)(+) 1–4a and X(+)BH(5)(+) 1–4d; X = NH(3), PH(3), H(2)O, and H(2)S) were calculated by using the ab initio method at the MP2/6-311+G** level. All of the dications 1–4a contain a four-coordinate boron atom with a three-center two-elec...
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| Главные авторы: | , , |
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| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
The National Academy of Sciences
2002
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC129682/ https://ncbi.nlm.nih.gov/pubmed/12370438 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.202476399 |
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