Influence of ligand structure on Fe(II) spin-state and redox rate in cytotoxic tripodal chelators

The Fe coordination chemistry of several tripodal aminopyridyl hexadentate chelators is reported along with cytotoxicity toward cultured Hela cells. The chelators are based on cis, cis-1,3,5-triaminocyclohexane (tach) with three pendant –CH(2)–2-pyridyl groups where 2-pyridyl is R-substituted thus a...

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Detalhes bibliográficos
Main Authors: Childers, Matt L., Cho, Joonhyung, Regino, Celeste A. S., Brechbiel, Martin W., DiPasquale, Antonio G., Rheingold, Arnold L., Torti, Suzy V., Torti, Frank M., Planalp, Roy P.
Formato: Artigo
Idioma:Inglês
Publicado em: 2007
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2238680/
https://ncbi.nlm.nih.gov/pubmed/17900698
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jinorgbio.2007.07.039
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