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Biosynthesis of the enediyne antitumor antibiotic C-1027 involves a new branching point in chorismate metabolism
C-1027 is an enediyne antitumor antibiotic composed of four distinct moieties: an enediyne core, a deoxy aminosugar, a β-amino acid, and a benzoxazolinate moiety. We now show that the benzoxazolinate moiety is derived from chorismate by the sequential action of two enzymes—SgcD, a 2-amino-2-deoxyiso...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2206564/ https://ncbi.nlm.nih.gov/pubmed/18182490 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0708750105 |
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