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Total Synthesis of (+)-Asperazine
The first total synthesis of the structurally novel cyclotryptophan alkaloid asperazine is reported. The central step in the synthetic sequence is a diastereoselective intramolecular Heck reaction in which the substituent controlling stereoselection is external to the ring being formed. This synthes...
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| Hlavní autoři: | , |
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| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2001
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1987397/ https://ncbi.nlm.nih.gov/pubmed/11562240 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2007.05.127 |
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