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C-Metalated Nitriles: Electrophile-Dependent Alkylations and Acylations
Sequential carbonyl addition-conjugate addition of Grignard reagents to 3-oxocyclohex-1-ene-1-carbonitrile generates C-magnesiated nitriles whose alkylation stereoselectivities intimately depend on the nature of the electrophile. Alkylating these C-magnesiated nitriles with alkyl halides, sulfonates...
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| Huvudupphovsmän: | , , , |
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| Materialtyp: | Artigo |
| Språk: | Inglês |
| Publicerad: |
2006
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| Ämnen: | |
| Länkar: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1896272/ https://ncbi.nlm.nih.gov/pubmed/16468790 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo052102j |
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