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Effect of carbonates/phosphates as nucleophilic catalysts in dimethylformamide for efficient cyanosilylation of aldehydes and ketones

Cyanosilylation of aldehydes and aliphatic ketones can be carried out in dimethylformamide even without the use of any catalyst. In the presence of nucleophilic catalysts such as carbonate and phosphate salts, the reaction rate is significantly enhanced.

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Bibliografske podrobnosti
Main Authors: Prakash, G. K. Surya, Vaghoo, Habiba, Panja, Chiradeep, Surampudi, Vijayalakshmi, Kultyshev, Roman, Mathew, Thomas, Olah, George A.
Format: Artigo
Jezik:Inglês
Izdano: National Academy of Sciences 2007
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC1805593/
https://ncbi.nlm.nih.gov/pubmed/17360603
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0611309104
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