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Chiral imine copper chloride-catalyzed enantioselective desymmetrization of 2-substituted 1,2,3-propanetriols

Catalytic enantioselective desymmetrization of meso-2-substituted glycerols has been developed to secure a novel synthetic route to chiral tertiary alcohols. The transformation has been realized by monobenzoylation using benzoyl chloride and triethylamine in the presence of the imine ligand (25)-CuC...

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Sonraí Bibleagrafaíochta
Main Authors: Jung, Byunghyuck, Kang, Sung Ho
Formáid: Artigo
Teanga:Inglês
Foilsithe: National Academy of Sciences 2007
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC1785247/
https://ncbi.nlm.nih.gov/pubmed/17242359
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0607865104
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