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First total syntheses of (Z)-15-methyl-10-hexadecenoic acid and the (Z)-13-methyl-8-tetradecenoic acid

The first total syntheses for the (Z)-15-methyl-10-hexadecenoic acid and the (Z)-13-methyl-8-tetradecenoic acid were accomplished in seven steps and in 31–32% overall yields. The (trimethylsilyl)acetylene was the key reagent in both syntheses. It is proposed that the best synthetic strategy towards...

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Hlavní autoři: Carballeira, Néstor M., Montano, Nashbly, Padilla, Luis F.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2006
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC1764626/
https://ncbi.nlm.nih.gov/pubmed/17125759
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.chemphyslip.2006.10.003
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