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Reaction mechanism of guanidinoacetate methyltransferase, concerted or step-wise

We describe a quantum mechanics/molecular mechanics investigation of the guanidinoacetate methyltransferase catalyzed reaction, which shows that proton transfer from guanidinoacetate (GAA) to Asp-134 and methyl transfer from S-adenosyl-l-methionine (AdoMet) to GAA are concerted. By self-consistent-c...

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Autori principali: Zhang, Xiaodong, Bruice, Thomas C.
Natura: Artigo
Lingua:Inglês
Pubblicazione: National Academy of Sciences 2006
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC1637550/
https://ncbi.nlm.nih.gov/pubmed/17053070
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0607503103
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