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Establishing the Kinetic Competency of the Cationic Imine Intermediate in Nitroalkane Oxidase
The flavoprotein nitroalkane oxidase catalyzes the oxidation of neutral nitroalkanes to the corresponding aldehydes and ketones. Cyanide inactivates the enzyme during turnover in a concentration-dependent fashion. Mass spectrometry of the flavin from enzyme inactivated by cyanide in the presence of...
Shranjeno v:
| Main Authors: | , , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2005
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1630679/ https://ncbi.nlm.nih.gov/pubmed/15713081 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja043542f |
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