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Establishing the Kinetic Competency of the Cationic Imine Intermediate in Nitroalkane Oxidase

The flavoprotein nitroalkane oxidase catalyzes the oxidation of neutral nitroalkanes to the corresponding aldehydes and ketones. Cyanide inactivates the enzyme during turnover in a concentration-dependent fashion. Mass spectrometry of the flavin from enzyme inactivated by cyanide in the presence of...

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Detalhes bibliográficos
Main Authors: Valley, Michael P., Tichy, Shane E., Fitzpatrick, Paul F.
Formato: Artigo
Idioma:Inglês
Publicado em: 2005
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC1630679/
https://ncbi.nlm.nih.gov/pubmed/15713081
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja043542f
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