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Direct spectroscopic detection of a C-H-cleaving high-spin Fe(IV) complex in a prolyl-4-hydroxylase
The Fe(II)- and α-ketoglutarate (αKG)-dependent dioxygenases use mononuclear nonheme iron centers to effect hydroxylation of their substrates and decarboxylation of their cosubstrate, αKG, to CO(2) and succinate. Our recent dissection of the mechanism of taurine:αKG dioxygenase (TauD), a member of t...
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| Main Authors: | , , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
National Academy of Sciences
2006
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1578498/ https://ncbi.nlm.nih.gov/pubmed/17003127 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0604005103 |
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