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Stereoselective construction of cis-2,6-disubstituted tetrahydropyrans via an intramolecular bismuth-mediated oxa-conjugate addition reaction
The intramolecular oxa-conjugate addition of tethered triethylsilyloxy substituted α,β-unsaturated ketones mediated by bismuth(III) nitrate pentahydrate provides a mild and efficient method for the stereoselective construction of cis-2,6-disubstituted tetrahydropyrans.
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| Hauptverfasser: | , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2005
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1463892/ https://ncbi.nlm.nih.gov/pubmed/16710442 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2005.06.100 |
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