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Binding of 5′-GTP to the C-terminal FeS cluster of the radical S-adenosylmethionine enzyme MoaA provides insights into its mechanism

The first step in molybdenum cofactor biosynthesis, the conversion of 5′-GTP to precursor Z, an oxygen-sensitive tetrahydropyranopterin is catalyzed by the S-adenosylmethionine (SAM)-dependent enzyme MoaA and the accessory protein MoaC. This reaction involves the radical-initiated intramolecular rea...

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Bibliografiska uppgifter
Huvudupphovsmän: Hänzelmann, Petra, Schindelin, Hermann
Materialtyp: Artigo
Språk:Inglês
Publicerad: National Academy of Sciences 2006
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC1458979/
https://ncbi.nlm.nih.gov/pubmed/16632608
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0510711103
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