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Evidence for C–H cleavage by an iron–superoxide complex in the glycol cleavage reaction catalyzed by myo-inositol oxygenase
myo-Inositol oxygenase (MIOX) activates O(2) at a mixed-valent nonheme diiron(II/III) cluster to effect oxidation of its cyclohexan-(1,2,3,4,5,6-hexa)-ol substrate [myo-inositol (MI)] by four electrons to d-glucuronate. Abstraction of hydrogen from C(1) by a formally (superoxo)diiron(III/III) interm...
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| Hauptverfasser: | , , , , , , , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
National Academy of Sciences
2006
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1458843/ https://ncbi.nlm.nih.gov/pubmed/16606846 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0508473103 |
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