Evidence for C–H cleavage by an iron–superoxide complex in the glycol cleavage reaction catalyzed by myo-inositol oxygenase

myo-Inositol oxygenase (MIOX) activates O(2) at a mixed-valent nonheme diiron(II/III) cluster to effect oxidation of its cyclohexan-(1,2,3,4,5,6-hexa)-ol substrate [myo-inositol (MI)] by four electrons to d-glucuronate. Abstraction of hydrogen from C(1) by a formally (superoxo)diiron(III/III) interm...

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Detalhes bibliográficos
Main Authors: Xing, Gang, Diao, Yinghui, Hoffart, Lee M., Barr, Eric W., Prabhu, K. Sandeep, Arner, Ryan J., Reddy, C. Channa, Krebs, Carsten, Bollinger, J. Martin
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2006
Assuntos:
Biological Sciences
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC1458843/
https://ncbi.nlm.nih.gov/pubmed/16606846
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0508473103
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