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Water dynamics and salt-activation of enzymes in organic media: Mechanistic implications revealed by NMR spectroscopy

Deuterium spin relaxation was used to examine the motion of enzyme-bound water on subtilisin Carlsberg colyophilized with inorganic salts for activation in different organic solvents. Spectral editing was used to ensure that the relaxation times were associated with relatively mobile deuterons, whic...

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Bibliografiske detaljer
Main Authors: Eppler, Ross K., Komor, Russell S., Huynh, Joyce, Dordick, Jonathan S., Reimer, Jeffrey A., Clark, Douglas S.
Format: Artigo
Sprog:Inglês
Udgivet: National Academy of Sciences 2006
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC1458637/
https://ncbi.nlm.nih.gov/pubmed/16585507
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0601113103
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