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Novel route to 5-position vinyl derivatives of thiolactomycin: Olefination vs. deformylation
Vinyl and diene derivatives of thiolactomycin have been prepared via Horner-Wadsworth-Emmons olefination from protected 5-formyl-3,5-dimethylthiotetronic acid. Several 4-position protecting groups and a variety of phosphonates were evaluated, with MOM protection and β-ketophosphonates yielding the h...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1450324/ https://ncbi.nlm.nih.gov/pubmed/16699591 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2006.03.058 |
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