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Convenient syntheses of [20,20,20-(2)H(3)]-arachidonic acid and [20,20-(2)H(2)]-20-hydroxyeicosatetraenoic acid
Deuterated arachidonic acid and 20-HETE were prepared in good overall yields and high stereoselectivities. Key transformations include a trans-specific vinyl dibromide reduction and Suzuki cross-couplings to a lithium borate or a 9-BBN borane. These standards are three and two mass units higher, res...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1414091/ https://ncbi.nlm.nih.gov/pubmed/16951707 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/jlcr.1039 |
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