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Synthesis of highly substituted allenylsilanes by alkylidenation of silylketenes

BACKGROUND: Allenylsilanes are useful intermediates in organic synthesis. An attractive, convergent but little used approach for their synthesis is the alkylidenation of stable silylketenes. Reactions thus far have been limited to the use of unsubstituted silylketenes (or equivalents) with stabilise...

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Autores principales: Marsden, Stephen P, Ducept, Pascal C
Formato: Artigo
Lenguaje:Inglês
Publicado: Beilstein-Institut 2005
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC1399453/
https://ncbi.nlm.nih.gov/pubmed/16542018
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1186/1860-5397-1-5
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