Synthesis of High Oxidation State Molybdenum Imido Heteroatom-Substituted Alkylidene Complexes

Reactions between Mo(NAr)(CHR)(Me(2)Pyr)-(OTPP) (Ar = 2,6-i-Pr(2)C(6)H(3), R = H or CHCMe(2)Ph, Me(2)Pyr = 2,5-dimethylpyrrolide, OTPP = O-2,3,5,6-Ph(4)C(6)H) and CH(2)=CHX where X = B(pin), SiMe(3), N-carbazolyl, N-pyrrolidinonyl, PPh(2), OPr, or SPh lead to Mo(NAr)(CHX)-(Me(2)Pyr)(OTPP) complexes...

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Autori principali: Townsend, Erik M., Kilyanek, Stefan M., Schrock, Richard R., Müller, Peter, Smith, Stacey J., Hoveyda, Amir H.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2013
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Article
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3785106/
https://ncbi.nlm.nih.gov/pubmed/24082360
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om400584f
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