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Direct Synthesis of Highly Substituted Pyrroles and Dihydropyrroles Using Linear Selective Hydroacylation Reactions

Rhodium(I) catalysts incorporating small bite‐angle diphosphine ligands, such as (Cy(2)P)(2)NMe or bis(diphenylphosphino)methane (dppm), are effective at catalysing the union of aldehydes and propargylic amines to deliver the linear hydroacylation adducts in good yields and with high selectivities....

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Bibliografische gegevens
Gepubliceerd in:Chemistry
Hoofdauteurs: Majhail, Manjeet K., Ylioja, Paul M., Willis, Michael C.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: John Wiley and Sons Inc. 2016
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Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5074311/
https://ncbi.nlm.nih.gov/pubmed/27106284
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201600311
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