Ab initio/GIAO-MP2-calculated structures and (11)B-(13)C NMR chemical shift relationship in hypercoordinate onium-carbonium dications and isoelectronic onium-boronium cations

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• Vicinal dihalonium ions: diprotonated and dimethylated chlorine [[Formula: see text] , [Formula: see text]] and bromine [[Formula: see text] , [Formula: see text]] dications
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• Attempted hydrogen–deuterium exchange of the protio-trimethyloxonium dication (CH(3))(3)OH(2+), study of methylating ability of (CH(3))(3)O(+) in superacids and theoretical investigations
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