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Nitroxyl and its anion in aqueous solutions: Spin states, protic equilibria, and reactivities toward oxygen and nitric oxide
The thermodynamic properties of aqueous nitroxyl (HNO) and its anion (NO(−)) have been revised to show that the ground state of NO(−) is triplet and that HNO in its singlet ground state has much lower acidity, pKa((1)HNO/(3)NO(−)) ≈ 11.4, than previously believed. These conclusions are in accord wit...
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| Asıl Yazarlar: | , |
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| Materyal Türü: | Artigo |
| Dil: | Inglês |
| Baskı/Yayın Bilgisi: |
The National Academy of Sciences
2002
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| Konular: | |
| Online Erişim: | https://ncbi.nlm.nih.gov/pmc/articles/PMC124232/ https://ncbi.nlm.nih.gov/pubmed/12032284 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.112202099 |
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