Nitroxyl and its anion in aqueous solutions: Spin states, protic equilibria, and reactivities toward oxygen and nitric oxide
The thermodynamic properties of aqueous nitroxyl (HNO) and its anion (NO(−)) have been revised to show that the ground state of NO(−) is triplet and that HNO in its singlet ground state has much lower acidity, pKa((1)HNO/(3)NO(−)) ≈ 11.4, than previously believed. These conclusions are in accord wit...
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| Publicat a: | Proc Natl Acad Sci U S A |
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| Autors principals: | , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
National Academy of Sciences
2002
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC124232/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/12032284/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.112202099 |
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