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Nitroxyl and its anion in aqueous solutions: Spin states, protic equilibria, and reactivities toward oxygen and nitric oxide

The thermodynamic properties of aqueous nitroxyl (HNO) and its anion (NO(−)) have been revised to show that the ground state of NO(−) is triplet and that HNO in its singlet ground state has much lower acidity, pKa((1)HNO/(3)NO(−)) ≈ 11.4, than previously believed. These conclusions are in accord wit...

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Главные авторы: Shafirovich, Vladimir, Lymar, Sergei V.
Формат: Artigo
Язык:Inglês
Опубликовано: The National Academy of Sciences 2002
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Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC124232/
https://ncbi.nlm.nih.gov/pubmed/12032284
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.112202099
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