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pH-controlled hydrogen-bonding (Short Communication)
The pH-dependence of the degree of hydrogen-bonding between a base and its conjugate acid is considered. When only a small proportion of the total base is complexed, the amount complexed is proportional to (1+coshp)(−1) where p=2.303 (pK(a)–pH), pK(a) being the dissociation constant of the conjugate...
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Autor principal: | |
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Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
1974
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Assuntos: | |
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1168448/ https://ncbi.nlm.nih.gov/pubmed/4462756 |
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