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Biradicals based on PROXYL containing building blocks for efficient dynamic nuclear polarization in biotolerant media

A versatile strategy for synthesizing tailored peptide based biradicals is presented. By labeling the protected amino acid hydroxyproline with PROXYL via the OH functionality and using this building block in solid phase peptide synthesis (SPPS), the obtained peptides become polarization agents for D...

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Autors principals: Kevin Herr, Mark V. Höfler, Henrike Heise, Fabien Aussenac, Felix Kornemann, David Rosenberger, Martin Brodrecht, Marcos de Oliveira, Jr., Gerd Buntkowsky, Torsten Gutmann
Format: Artigo
Idioma:Inglês
Publicat: Elsevier 2024-09-01
Col·lecció:Journal of Magnetic Resonance Open
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Accés en línia:http://www.sciencedirect.com/science/article/pii/S2666441024000074
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